Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 38, Pages 12061-12065Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403447
Keywords
copper; dual catalyst; enone; rhenium; trifluoromethyl
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Funding
- RIKEN
- NOVARTIS Foundation (Japan) for the Promotion of Science
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Trifluoromethylation of propargylic alcohols to provide (Z)-alpha-trifluoromethylated enones and beta-unsubstituted alpha-trifluoromethylated enones proceeded with high yield and selectivity in the presence of CuI/Re2O7. The Z isomer was formed under kinetic control, though it is less stable than the E isomer in terms of steric repulsion.
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