Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 38, Pages 12056-12060Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403993
Keywords
bioinorganic chemistry; environmental chemistry; enzymes; vanadium; X-ray absorption spectroscopy
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Funding
- Australian Research Council
- Australian Synchrotron Research Program
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A library of X-ray absorption near-edge structure (XANES) spectroscopic data for V-V, V-IV and V-III complexes with a broad range of biologically relevant ligand has been used to demonstrate that three-dimensional plots of key XANES parameters (pre-edge and edge energies; pre-edge and white line intensities) can be used for the prediction of V oxidation states and coordination numbers in biological or environmental matrices. The reliability of the technique has been demonstrated by re-analysis of the published XANES data for a V-V-dependent bromoperoxidase.
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