Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 45, Pages 14556-14568Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402599
Keywords
functionalization; molecular oxygen; oxidation; palladium; platinum
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Funding
- National Science Foundation [CHE-1012045, DGE-0718124]
- Department of Energy [DE-FG02-06ER15765]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1012045] Funding Source: National Science Foundation
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Knowledge of exactly how metal complexes react with molecular oxygen is still limited and this has hampered efforts to develop catalysts for oxidation reactions using O-2 as the oxidant and/or oxygen-atom source. A better understanding of the reactions of different types of metal complexes with O-2 will be of great utility in rational catalyst development. Reactions between molecular oxygen and Pd0-II and Pt0-IV complexes are reviewed here.
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