Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 23, Pages 6871-6874Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402682
Keywords
cation exchange; ligand field parameters; metal-organic frameworks; polarity index; solvation energy
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0006937]
- MINECO [CTQ2012-33826/BQU]
- NSF [1122374]
- MIT International Science and Technology Initiatives center
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We investigated which factors govern the critical steps of cation exchange in metal-organic frameworks by studying the effect of various solvents on the insertion of Ni2+ into MOF-5 and Co2+ into MFU-4l. After plotting the extent of cation insertion versus different solvent parameters, trends emerge that offer insight into the exchange processes for both systems. This approach establishes a method for understanding critical aspects of cation exchange in different MOFs and other materials.
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