Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 4, Pages 1463-1467Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405903
Keywords
carbazoles; cascade reaction; gold catalysis; hydroarylation; indoles
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Japan Society for the Promotion of Science for Young Scientists
- Grants-in-Aid for Scientific Research [23390025, 24689001] Funding Source: KAKEN
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Indole synthesis by a gold(I)-catalyzed intermolecular formal [4+2] reaction between 1,3-diynes and pyrroles has been developed. This reaction involves the hydroarylation of 1,3-diynes with pyrroles followed by an intramolecular hydroarylation to give the 4,7-disubstituted indoles. This reaction can also be applied to the synthesis of carbazoles when indoles are used as the nucleophiles instead of pyrroles.
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