Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 8, Pages 2169-2174Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304623
Keywords
cycloaddition; carbodiimides; carbon dioxide; diynes; rhodium
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT, Japan) [20675002]
- ACT-C from Japan Science and Technology Agency (JST)
- Grants-in-Aid for Scientific Research [25105714] Funding Source: KAKEN
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It has been established that a cationic rhodium(I)/H-8-binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio- and/or regioselective variants of these reactions are also disclosed.
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