Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 28, Pages 8571-8574Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402058
Keywords
azaphosphatranes; CO2 conversion; cyclic carbonates; green chemistry; organocatalysis
Categories
Funding
- French Ministry of Research [ANR-2010JCJC 7111]
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The endohedral functionalization of a molecular cage by an azaphosphatrane unit has allowed for the creation of highly engineered catalytic cavities for efficient conversion of CO2 into cyclic carbonates. Strong structure/activity/stability correlations have been demonstrated by careful adjustment of the size, shape, and electronic properties of the hemicryptophane host.
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