Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 17, Pages 4942-4947Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304840
Keywords
cycloaddition; diazo compounds; fluorine; in situ generation; pyrazolines
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The novel chemical reagent, C2F5CHN2, is generated in situ from C2F5CH2NH2HCl and sodium nitrite. It reacts with mono- and disubstituted electron-deficient alkenes at room temperature to afford C2F5-pyrazolines in excellent yields.
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