Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 20, Pages 6120-6125Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304731
Keywords
aminoalkylation; fullerenes; photooxidation; radicals; redox chemistry
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Funding
- Funding Program for Next Generation World-Leading Researchers [GR025]
- MEXT, Japan
- Grants-in-Aid for Scientific Research [26870120, 26105725] Funding Source: KAKEN
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The functionalization of fullerene has been extensively studied and various fullerene derivatives have been synthesized. We have succeeded in the functionalization of [60]fullerene by using -aminoalkyl radicals generated by visible-light-mediated single-electron oxidation of -silylamines as synthetic intermediates. In these reactions, the introduction of diarylamino groups, which are useful electron donors, has been easily achieved.
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