4.6 Article

Visible-Light- Mediated Addition of a-Aminoalkyl Radicals to [60]Fullerene by Using Photoredox Catalysts

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 20, Pages 6120-6125

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304731

Keywords

aminoalkylation; fullerenes; photooxidation; radicals; redox chemistry

Funding

  1. Funding Program for Next Generation World-Leading Researchers [GR025]
  2. MEXT, Japan
  3. Grants-in-Aid for Scientific Research [26870120, 26105725] Funding Source: KAKEN

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The functionalization of fullerene has been extensively studied and various fullerene derivatives have been synthesized. We have succeeded in the functionalization of [60]fullerene by using -aminoalkyl radicals generated by visible-light-mediated single-electron oxidation of -silylamines as synthetic intermediates. In these reactions, the introduction of diarylamino groups, which are useful electron donors, has been easily achieved.

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