Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 1, Pages 72-76Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201303602
Keywords
density functional calculations; ionic liquids; magnetic properties; structure elucidation
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Funding
- Spanish Ministerio de Ciencia e Innovacion [MAT2011-27573-C04]
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A new magnetic ionic liquid (MIL) with 3D antiferromagnetic ordering has been synthetized and characterized. The information obtained from magnetic characterization was supplemented by analysis of DFT calculations and the magneto-structural correlations. The result gives no evidence for direct iron-iron interactions, corroborating that the 3D magnetic ordering in MILs takes place via super-exchange coupling containing two diamagnetic atoms intermediaries.
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