4.6 Article

Nickel Hydroxide Nanoparticle Activated Semi-metallic TiO2 Nanotube Arrays for Non-enzymatic Glucose Sensing

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 46, Pages 15530-15534

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201301495

Keywords

electrooxidation; nanostructures; nickel; sensors; titanium

Funding

  1. National Natural Science Foundation of China [21005012, 21275026, 11004025, 11174046, 21005016]
  2. New Century Excellent Talents in the University of China [NCET-10-0305]
  3. Fundamental Research Fund for the Central Universities [N120505002, N120505006, N110805001, N110705002]
  4. DFG
  5. DFG Cluster of Excellence EAM

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Semi-metallic TiO2 nanotube arrays (TiOxCy NTs) have been decorated uniformly with Ni(OH)(2) nanoparticles without the aid of a polymer binder. The resulting hybrid nanotube arrays exhibit excellent catalytic activity towards non-enzymatic glucose electro-oxidation. The anodic current density of the glucose oxidation is significantly improved compared with traditional TiO2 nanotubes decorated with Ni(OH)(2). Moreover, the Ni(OH)(2)/TiOxCy NT-based electrode shows a fast response, high sensitivity, wide linear range, good selectivity and stability towards glucose electro-oxidation, and thus provides a promising and cost-effective sensing platform for non-enzymatic glucose detection.

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