Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 15, Pages 4664-4678Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201203707
Keywords
biomimetic catalysis; carbenes; cascade reactions; organocatalysis; umpolung
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Funding
- NRW International Graduate School of Chemistry
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This Concept article discusses the potential of oxidative carbene catalysis in synthesis and comprehensively covers pioneering studies as well as recent developments. Oxidative carbene catalysis can be conducted by using inorganic and organic oxidants. Applications in cascade processes, in enantioselective catalysis, and also in natural product synthesis are discussed.
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