Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 42, Pages 14010-14017Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201302576
Keywords
asymmetric reactions; CH activation; chirality; stereoselective CH activation; transition-metal catalysis
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A niche topic in the past decade, the asymmetric CH bond activation has been attracting growing interest over the last few years. Particularly significant advances have been achieved in the field of direct, stereoselective transformations of C(sp(2))H bonds. This Concept article intends to showcase different types of asymmetric C(sp(2))H bond activation reactions, emphasising both the nature of the stereo-discriminating step and the variability of valuable scaffolds that could be rapidly constructed by means of such strategies.
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