Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 2, Pages 381-384Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304031
Keywords
cooperativity; dicarboxylic acid; fluorescence; molecular recognition; nonlinear response
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Funding
- [25810051]
- Grants-in-Aid for Scientific Research [25810051] Funding Source: KAKEN
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A novel tetraphenylethene-based fluorescence (FL) chemosensor exhibits nonlinear turn-on FL switching though cooperative binding of l-tartarate, where its convergent binding to form cyclic substructures is responsible for the FL increase. This binding scheme achieves selective detection of dicarboxylates over monocarboxylates, thus is potentially applicable to the preliminary screening for metabolic disorders.
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