Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 17, Pages 5442-5449Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201202452
Keywords
iron; lamellar structures; mesostructures; nanostructures; organic; inorganic hybrid composites
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Funding
- National Natural Science Foundation of China [91122016]
- National Basic Research Program of China [2011CB808402, 2009CB930401]
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We have demonstrated a new and facile bottom-up protocol for the effective synthesis of oval-shaped iron oxide/ethylene glycol (FeOx/EG) mesostructured nanosheets. Deprotonated ethylene glycol molecules are intercalated into iron oxide layers to form an interlayer distance of 10.6 angstrom. These materials display some peculiar magnetic properties, such as the low Morin temperature TM and ferromagnetism below this TMvalue. CdSe/ZnS nanoparticles can be loaded onto these mesostructured nanosheets to produce nanocomposites that combine both magnetic and fluorescence functions. In addition, iron oxide/propanediol (or butanediol) mesostructured materials with increased interlayer distances can also be synthesized. The developed synthetic strategy may be extended toward the creation of other ultrathin mesostructured nanosheets.
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