Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 18, Issue 33, Pages 10092-10142Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201201539
Keywords
C?H activation; ions; radicals; saturated cyclic amine; transition metals; a-functionalization
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Funding
- University of Antwerp (IOF and BOF)
- Hercules foundation
- Janssen Research & Development (Janssen Pharmaceutica N.V.)
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Recent advances in synthetic methods for the direct a-functionalization of saturated cyclic amines are described. Methods are categorized according to the in situ formed reactive intermediate (a-amino cation, a-amino anion, and a-amino radical). Transition-metal-catalyzed reactions involving other intermediates have been treated as a separate and fourth class.
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