Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 3, Pages 818-827Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201203145
Keywords
covalent organic frameworks; crystal engineering; functionalization; metal-organic frameworks; self-assembly
Categories
Funding
- NSF CAREER award [CHE-1056657]
- NSF
- Sloan Research Fellowship
- Cottrell Scholar Award from Research Corporation for Science Advancement
- 3M Nontenured Faculty Award
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1056657] Funding Source: National Science Foundation
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Framework materials have attracted intense interest for gas storage, separations, catalysis, and other applications as a consequence of their periodicity, high specific surface area, and rational synthesis. Cocrystallizing multiple monomers with identical linking chemistry represents an emerging route to access materials with increased complexity and advanced functions. This Concept Article highlights three strategies for framework synthesis that employ mixtures of monomers with 1) identical linking geometries, 2) different linking geometries, or 3) in which one monomer is truncated with respect to the other. These approaches offer a diverse toolbox to modify framework topology, incorporate active functionality, and rationally control crystallite size and morphology.
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