4.6 Article

Al-Catalyzed Facile Construction of Quaternary C-C Bonds by the Allylic Substitution of Tertiary Alcohols: A Concise and Formal Synthesis of (±)-Mersicarpine

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 18, Issue 32, Pages 9784-9788

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201201344

Keywords

allylic compounds; aluminum; Friedel-Crafts reaction; Grignard reaction; mersicarpine; quaternary carbon; Wolff-Kishner reduction

Funding

  1. Hundred Talent Program of CAS
  2. State Key Laboratory of Bio-organic and Natural Products Chemistry [09182]

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