Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 19, Issue 2, Pages 459-463Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201203859
Keywords
acridones; aminobenzophenone; bipyridine; copper; oxidation; total synthesis
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Funding
- National Science Council of Republic of China [NSC-101-2628-M-007-004]
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A good move: A copper-catalyzed intramolecular oxidative C H functionalization of 2-aminobenzophenone affords two regioisomeric acridones (see scheme). The reaction involves an unusual pseudo-1,2-migration of R-2 group(s) on the arene ring (bpy=2,2'-bipyridine, DMAc=dimethylacetimide).
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