Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 18, Issue 47, Pages 14968-14973Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201202978
Keywords
cucurbit[8]uril; host-guest molecules; molecular imprinting; nanochemistry; redox chemistry
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Funding
- Natural Science Foundation of China [20974059, 50973051]
- Foundation for Innovative Research Groups [21121004]
- DFG-NSFC Transregio SFB [TRR61]
- Science Foundation of China Postdoctor [20110490369]
- Tsinghua University Initiative Scientific Research Program [2009THZ02230]
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Stable multilayer films with cucurbit[8]uril have been fabricated on the basis of the alternating layer-by-layer assembly of a novel side-chain pseudopolyrotaxane and a photoreactive polyanion. The as-prepared multilayer films exhibit good properties as surface-imprinted multilayers, because cucurbit[8]uril molecules that are locked inside the multilayers can act as nanocontainers with specific binding to certain guest molecules, and the loading and release of the guest is redox-controllable and reversible.
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