Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 18, Issue 16, Pages 4965-4973Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102008
Keywords
click chemistry; conjugated polymers; graphene; photoelectron spectroscopy; Raman spectroscopy
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Funding
- Spanish Ministry of Science and Innovation
- MICINN [MAT2009-09335, CTQ2010-14982, CSD2007-41, MAT2008-1497nan, MAT2010-17720]
- Comunidad Autonoma de Madrid [S2009/MAT-1467]
- UCM-BSCH [GR58/08]
- CSIC
- Rafael Calvo Rodes scholarship program
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Graphene flakes covalently modified with a conjugated polymer, poly[(9,9-dihexylfluorene)-co-alt-(9,9-bis-(6-azidohexyl)fluorene)] (PFA), were efficiently synthesised by a Cu-catalysed Huisgen 1,3-dipolar cycloaddition between alkyne-modified graphene and an azide-functionalised polymer. Two approaches for the modification of graphene with alkyne groups were investigated (coupling with a diazonium salt generated in situ or an amidation reaction) and the optimum conditions determined. The success of the click-coupling approach was confirmed by FTIR, 1H NMR, Raman, and X-ray photoelectron spectroscopy (XPS). The absorption and emission spectra of the click product show a strong solvent dependency.
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