Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 25, Pages 6890-6899Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201003694
Keywords
asymmetric synthesis; bifunctional catalysts; molecular recognition; organocatalysis
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Funding
- Carlsberg Foundation
- OChem Graduate School
- Spanish Government [CTQ-2009-12168]
- CAM [AVANCAT CS2009/PPQ-1634]
- Spanish Ministerio de Educacion
- Spanish Ministerio de Ciencia e Innovacion
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In this minireview, squaramides are presented from their roots as artificial anion receptors in molecular recognition studies to their recent advances as powerful bifunctional hydrogen-bonding catalysts in asymmetric organocatalysis. The main features of the squaramido functionality and the direct comparison with the analogous ureas and thioureas are also discussed.
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