Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 51, Pages 14326-14346Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201101486
Keywords
electrochemistry; conducting materials; lithium; lithium-ion batteries
Categories
Funding
- National Research Foundation [NRF-2009-EWT-CERP001-036, NRF-CRP4-2008-03]
Ask authors/readers for more resources
This paper presents an overview of the various types of lithium salts used to conduct Li+ ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid-electrolyte interface (SEI) formation towards carbonaceous anodes and the effect of anions on the aluminium current collector. The physicochemical and functional parameters relevant to electrochemical properties, that is, electrochemical stabilities, are also presented. The new types of lithium salts, such as the bis(oxalato) borate (LiBOB), oxalyldifluoroborate (LiODFB) and fluoroalkylphosphate (LiFAP), are described in detail with their appropriate synthesis procedures, possible decomposition mechanism for SEI formation and prospect of using them in future generation lithium-ion batteries. Finally, the state-of-the-art of the system is given and some interesting strategies for the future developments are illustrated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available