Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 20, Pages 5652-5660Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201003711
Keywords
boron; catalysis; copper; functional-group transformations; water chemistry
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Funding
- National Natural Science Foundation of China [20972083]
- Ministry of Science and Technology of China [2009ZX09501-004]
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A simple and general copper-catalyzed method has been developed for transformations of various functional groups (-I, -N-3, -SO2R, -OH, -NH2, and -NO2) on aromatic rings from arylboronic acids in water under air. The protocol uses cheap and readily available inorganic salts (KI, NaN3, NaSO2R, NaOH, NaNO2) and aqueous ammonia as the functionalgroup sources, simple Cu2O/NH3 as the catalyst system, environmentally friendly water as the solvent, and oxygen in air as the oxidant. Importantly, the copper catalyst system in water was recyclable. This study should provide a useful strategy for interconversions of the functional groups on aromatic rings.
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