Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 44, Pages 12294-12301Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201102348
Keywords
chirality; gold; metallocorroles; NMR spectroscopy; X-ray diffraction
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Funding
- DFG
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Corrole complexes with gold(I) and gold(III) were synthesized and their structural, photophysical, and electrochemical properties investigated. This work includes the X-ray crystallography characterization of gold(I) and gold(III) complexes, both chelated by a corrole with fully brominated beta-pyrrole carbon atoms. The mononuclear and chiral gold(I) corrole appears to be the first of its kind within the porphyrinoid family, while the most unique property of the gold(III) corrole is that it displays phosphorescence at ambient temperatures.
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