Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 10, Pages 2923-2930Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201002235
Keywords
NMR spectroscopy; optical properties; oriented attachment; poly-N-vinylpyrrolidone; ZnO mesocrystals
Categories
Funding
- BASF
- Deutsche Forschungsgemeinschaft through the Cluster of Excellence Engineering of Advanced Material initiative at the Friedrich Alexander University of Erlangen-Nuremberg
Ask authors/readers for more resources
Polymers and coordinating solvents have been shown to serve as templating agents to assist the precipitation of ZnO nanoparticles and address their morphology. In this work we show for the first time that a difference in the coordination strength between the polymer (poly-N-vinylpyrrolidone (PVP)) and the two Zn-II precursor salts (nitrate and acetate) is able to promote or suppress the formation of mesocrystalline structures and even more importantly to tune their three-dimensional organization. On the basis of FTIR and C-13 NMR spectroscopic studies, we propose that not only the polymer (PVP) but also the solvent (DMF) play a key role as directing agents.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available