Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 15, Pages 4283-4290Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201001901
Keywords
cycloaddition; N ligands; reactivity; small ring systems; X-ray diffraction
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Funding
- Deutsche Forschungsgemeinschaft
- Deutscher Akademischer Austausch Dienst
- Alexander von Humboldt Foundation
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Heteroleptic chlorosilylene (PhC(NtBu)(2)SiCl) (1) reacts with unsaturated organic compounds under oxidative addition. Reactions of 1 with cyclooctatetraene (COT) and a diimine afford [1+4]-cycloaddition products 3 and 6, respectively. In the case of COT, one Si-N bond of the amidinato ligand is cleaved, resulting in tetracoordinate silicon, whereas with a diimine a penta-coordinate silicon is formed. Treatment of 1 with ArN=C=NAr (Ar=2,6-iPr(2)C(6)H(3)) yields silaimine complex 4 with cleavage of one of the C=N bonds. The facile isolation of silaimine complexes is probably due to the kinetic protection afforded by the bulky Ar moiety. When 1 is treated with tertbutyl isocyanate, cleavage of the C=O bond is observed, which leads to formation of the four-membered Si2O2 cycle 5. The same product is formed when 1 is allowed to react with trime-thylamine N-oxide. When 1 is treated with diphenyl disulfide, cleavage of the S-S bond occurs to form 7. All products have been characterized by multinuclear NMR spectroscopy, EI mass spectrometry, and elemental analysis. In addition, the molecular structures of 3-6 have been determined by single-crystal X-ray diffraction studies. Collectively, these results suggest that owing to the presence of the lone pair of electrons, the propensity of 1 to undergo oxidative addition is very high.
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