Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 8, Pages 2435-2441Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201002862
Keywords
gels; molecular recognition; polymers; self-assembly; supramolecular chemistry
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Funding
- National Natural Science Foundation of China [20625206, 20772126]
- Chinese Academy of Sciences
- National Basic Research Program of China [2011CB932501]
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Self-complementary monomer 1, which combines a macrotricyclic polyether and two dibenzylammonium ions together, was synthesized, and its self-assembly into supramolecular polymer networks by host-guest interactions was studied. For the purpose of comparative study, two model molecules 2 and 3 were also prepared. It was found that model molecule 2 and dibenzylammonium ion 4 form a 1: 2 complex in solution and in the solid state, which afforded a model system for the investigation of the assembly behavior of monomer 1. Consequently, the H-1 NMR spectrum of 1 in CD3CN showed characteristic proton signals similar to the model system, which suggested that 1 self-assembles into a supramolecular polymer network. Formation of the supramolecular polymer was further evidenced by the MALDI-TOF MS spectrum, viscometry, and dynamic light-scattering (DLS) experiments. Moreover, it was found that the decomposition and re-formation of the supramolecular polymer could be chemically controlled by the use of triethylamine and trifluoroacetic acid. Interestingly, the supramolecular polymer forms an organogel both in CD3CN and in 1: 1 (v/v) CDCl3/CD3CN, and reversible thermo-and pH-induced gel-sol transitions were also found. The presented work will provide a new strategy for the construction of supramolecular polymers with specific structures and properties.
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