Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 30, Pages 8404-8413Publisher
WILEY-BLACKWELL
DOI: 10.1002/chem.201100655
Keywords
acetals; aldehydes; heterogeneous catalysis; hydrosilylation; nanoparticles; palladium
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Funding
- Tekes (Enabling Synthesis Technologies platform)
- University of Jyvaskyla, Department of Chemistry
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A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1) enolsilanes of high isomeric purity, 2) saturated aldehydes or ketones, or 3) the corresponding saturated acetals from alpha,beta-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol.
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