Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 16, Issue 32, Pages 9789-9795Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000278
Keywords
copper; cyclopropanation; gold; heterogeneous catalysis; metal-organic frameworks
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The copper and gold metal organic frameworks (MOFs) [Cu-3(BTC)(2)(H2O)(3)](n), [Cu-3(BTC)(2)] (BTC=benzene-1.3.5-tricarboxylate). and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities Pus type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts These MOFs can help to budge the gap between homogeneous and heterogeneous catalysis.
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