Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 16, Issue 18, Pages 5260-5273Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200903410
Keywords
asymmetric synthesis; organocatalysis; rearrangement; sigmatropic rearrangement; stereoselective catalysis
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Funding
- Spanish Ministry of Science and Innovation (MICINN) [AYA2006-15648-C02-01, AYA2009-13920-C02-02]
- Spanish Ministry of Foreign Affairs and Cooperation
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Rearrangement reactions often lead to the regio- and stereoselective formation of carbon carbon or carbon-heteroatom bonds, and allow the construction of otherwise hard-to-access molecular frameworks. Research disclosed in the present decade, especially in the last two years, has shown that organocatalytic modes of activation can be successfully applied to a variety of rearrangements. In this Minireview we discuss the advances achieved so far in asymmetric organocatalytic rearrangement reactions.
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