Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 16, Issue 24, Pages 7143-7163Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000621
Keywords
coordination chemistry; conjugation; copper; phosphorus heterocycles; supramolecular chemistry
Categories
Funding
- Ministere de la Recherche et de l'Enseignement Superieur
- Institut Universitaire de France
- CNRS
- ANR [Phoshelix-137104]
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The reaction of U-shaped, bimetallic, Cu-I complexes, assembled from a heteroditopic pincer, with cyano-capped pi-conjugated linkers gives a straightforward access to pi-stacked metallocyclophanes in good yields. In these assemblies, the it-walls have an almost face-to-face arrangement. The versatility of this rational supramolecular synthesis is demonstrated with the use of linkers that have nanoscale lengths (up to 27.7 angstrom), different chemical compositions (oligo(para-phenylenevinylene)s OPVs, oligo(phenylene)s, oligo(phenylethynylene)s), and alternative geometries (linear, angular). Linkers that incorporate an internal pyridyne moiety can also be employed. X-ray diffraction studies revealed that the metallocyclophanes based on linear linkers self-organize into infinite pi-stacked columns in the solid state with intermolecular distances of about 3.6 angstrom. This approach, based on coordination-driven self-assembly, provides a novel and rational strategy for the stacking of extended pi-systems in the solid state.
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