Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 17, Issue 1, Pages 384-391Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201000691
Keywords
batteries; nanostructures; porous materials; pyrolysis; vanadium
Categories
Funding
- National Basic Research Program of China [2009CB939901]
- National Natural Science Foundation of China [90922016, 10979047]
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New-phased metastable V2O3 porous urchinlike micronanostructures were first fabricated on a large scale by a simple top-down strategy of pyrolyzing a vanadyl ethylene glycolated precursor in the absence of any templates or matrices. The pyrolysis mechanism was clearly revealed by synchrotron vacuum ultraviolet (VUV) photoionization mass spectra for the first time. The new-phased metastable V2O3 exhibits a body-centered cubic bixbyite structure and shows structural evolution from metastable cubic symmetry to thermodynamically stable rhombohedral symmetry V2O3 (R) above 510 degrees C. Furthermore, the prepared V2O3 porous urchinlike micronanostructures, as anode materials in agueous lithium ion batteries, exhibit improved electrochemical properties with relatively high first discharge capacity and better cycle retention relative to thermodynamically stable V2O3 (R), which is derived from its unique microscopic crystal structure and macroscopic 3D framework with rigid morphology, porous structure, and high specific surface area.
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