Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 16, Issue 39, Pages 11985-11992Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201001228
Keywords
carbenes; density functional calculations; Lewis acids; Lewis bases; platinum
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Funding
- Fonds der Chemischen Industrie
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Syntheses of the first heteroleptic N-heterocyclic carbene (NHC)-phosphane platinum(0) complexes and formation of the corresponding Lewis acid base adducts with aluminum chloride is reported. The influence of N-heterocyclic carbenes on tuning the Lewis basic properties of the metal complexes was judged from spectroscopic, structural, and computational data. Conclusive experimental evidence for the enhanced Lewis basicity of NHC-containing complexes was provided by a transfer reaction.
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