Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 16, Issue 46, Pages 13572-13589Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201001478
Keywords
Ar-C bonds; aromatic substitution; arylation; C-based leaving groups; cleavage reactions
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The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics.
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