Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 15, Issue 42, Pages 11058-11076Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200902236
Keywords
asymmetric synthesis; Bronsted catalysis; domino reactions; Michael addition; organocatalysis
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The catalytic aza-Michael addition is an important reaction within synthetic organic chemistry, given the significance of the biologically and synthetically interesting products, such as beta-amino acids and beta-lactams. In the last decade organocatalysis emerged as a powerful tool in asymmetric synthesis and had a large impact on the development of asymmetric and catalytic conjugate additions of nitrogen nucleophiles to Michael acceptors. In this review a first summary of the recent rapid progress of asymmetric organocatalyzed aza-Michael reactions is presented.
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