Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 15, Issue 11, Pages 2476-2485Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801968
Keywords
anions; conjugation; Group 14 elements; multiple bonds; Si ligands; silicon
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Funding
- Deutsche Forschungsgemeinschaft (DFG)
- Fonds der Chemischen Industrie (FCI)
- Karl-Winnacker-Fonds of the Aventis Foundation
- Dr. Otto Rohm-Gedachtnisstiftung.
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Anionic compounds capable of transferring a silicon double bond are summarized following an introduction to the differences between alkenes and their heavier homologues. The main focus is on reagents with Si=Si moieties and their applications towards main-group and transition-metal electrophiles, as well as their reactivity towards organic compounds, but a few recently reported derivatives with Si=C and Si=P bonds are also included.
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