Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 15, Issue 41, Pages 10924-10929Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200900841
Keywords
fullerenes; macrocycles; porphyrinoids; template synthesis; supramolecular chemistry
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Funding
- Ministry of Science and Higher Education [PBZ-KBN-118rF09/2004]
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Insertion of PCl3 into 5,10,15,20-tetraaryl-21-telluraporphyrin leads to a phosphorus complex of N-fused dihydrotelluraporphyrin with an inverted tellurophene ring. Its CNN coordination core places the macrocycle in the family of contracted carbaporphyrinoids. A cycle of direct transformations affords an elegant triangle of three mutually convertible N-fused porphyrinoids, with distinct spectroscopic features: antiaromatic, nonaromatic and aromatic. The nonaromatic species has a dome shaped skeleton which forms in the solid state a ball and socket structure with C-60.
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