Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 14, Issue 27, Pages 8177-8182Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200800190
Keywords
carbon nitrides; covalent frameworks; layered compounds; salt melt; solid-state structures
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Funding
- Max Planck Society
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Herein we report the synthesis of a crystalline graphitic carbon nitride, or g-C3N4, obtained from the temperature-induced condensation of dicyandiamide (NH2C(=NH)NHCN) by using a salt melt of lithium chloride and potassium chloride as the solvent. The proposed crystal structure of this g-C3N4 species is based on sheets of hexagonally arranged s-heptazine (C6N7) units that are held together by covalent bonds between C and N atoms which are stacked in a graphitic, staggered fashion, as corroborated by powder X-ray diffractometry and high-resolution transmission electron microscopy.
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