Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 15, Issue 4, Pages 878-884Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200802126
Keywords
dyes/pigments; optical properties; perylene monoimides; rainbow; solar cells
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Funding
- Deutsche Forschungsgenicinschaft (DFG) [1355]
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Perylene dyes have been widely used as photoreceptors in organic photovoltaics because of their outstanding photo-, thermal and chemical stability as well as their excellent photophysical properties. Herein we describe a novel generation of perylene dyes based on N-(2.6-diisopropylphenyl)-perylene-3,4-dicarboximide. The optical properties of these novel perylenes can be finely tuned via the substituents in the 1-, 6- and 9-positions of the perylene core. The facile synthesis, tunable orbital and absorption properties, and electrochemical potentials help us to design efficient perylene sensitizers for solar-cell applications.
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