Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 14, Issue 31, Pages 9641-9646Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200801610
Keywords
catalysis; flow synthesis; gold; hydrosilylation; microwave
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC) [CRDPJ 338330-06]
- Ontario Graduate Scholarship (OGS)
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Thin gold films on the surface of lass capillaries have proven to be highly, active catalysts for the rapid hydrosilylation of alkynes that are flowed through the reactor while being heated by microwave irradiation. The films are able to be reused at least five times with no loss of activity and with no detectable levels of gold showing up in the hydrosilylated products.
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