Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 14, Issue 33, Pages 10364-10368Publisher
WILEY-BLACKWELL
DOI: 10.1002/chem.200801728
Keywords
cyclometalation; hydrogenation; iridium; P ligands; pincer complexes
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Funding
- Israel Science Foundation [866/06]
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The manuscript describes the synthesis and full characterization of a new PC(sp(3))P-based cyclometalated Ir-III complex that manifests all exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C-(sp(3))-metalated compounds.
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