Journal
CHEMISTRY OF MATERIALS
Volume 26, Issue 8, Pages 2544-2550Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm4038654
Keywords
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Funding
- Hong Kong University Grants Committee Area of Excellence Scheme [AoE/P-03-08]
- General Research Fund [CityU 101212]
- Research Grants Council of the Hong Kong SAR, China [T23-713/11]
- University Postgraduate Studentship
- Research Tuition Scholarship
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A simple design strategy for a new class of stable, vacuum-sublimable, and strongly emissive sky-blue neutral phosphorescent Re(I) phenanthroline complexes {Re(R(2)phen)(CO)(3)[CNB(C6F5)(3)]} is reported. These complexes show intense bluish green emission in CH2Cl2 solution with the highest emission quantum yield and bluest emission ever reported for the neutral Re(I) amine complexes. In the solid state, they display sky-blue emission. The electroluminescent properties of devices containing these complexes have also been investigated.
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