Journal
CHEMISTRY OF MATERIALS
Volume 25, Issue 9, Pages 1922-1926Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm400579k
Keywords
cobalt hydroxide; Co(OH)(2); electrodeposition; oxygen evolution reaction; oxygen evolution catalyst
Funding
- U.S. Department Of Energy, Office of Basic Sciences [DE-FG02-08ER46518]
- U.S. Department of Energy (DOE) [DE-FG02-08ER46518] Funding Source: U.S. Department of Energy (DOE)
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Films of beta-Co(OH)(2) with a dense microcone morphology are electrodeposited at room temperature by reducing tris(ethylenediamine)cobalt(III) in alkaline solution. The synthesis exploits the fact that the kinetically inert Co(III) complex of ethylenediamine (en) is 35 orders of magnitude more stable than the kinetically labile Co(II) complex. [Co(en)(3)](3+) is therefore stable in alkaline solution, but [Co(en)3](2+) reacts with excess hydroxide ion to produce beta-Co(OH)(2). The electrodeposited beta-Co(OH)(2) is an active catalyst for the oxygen evolution reaction. Raman spectroscopy suggests that the surface of beta-Co(OH)(2) is converted to CoOOH at the potentials at which oxygen evolution occurs.
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