Journal
CHEMISTRY OF MATERIALS
Volume 25, Issue 6, Pages 981-988Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm400123d
Keywords
porous aromatic frameworks; bifunctionalized solids; heterogeneous catalysis; organocatalysis; one-pot tandem reaction
Funding
- Direccion General de Investigacion Cientifica y Tecnica of Spain [MAT2011-29020-C02-02, 2009-CSD-0050-MULTI-CAT]
- CSIC for a contract of Junta de Ampliacion de Estudios program
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We described the use of one porous polymeric aromatic framework (PPAF) with a 9,9'-spiro-bisfluorene unit as a support in heterogeneous catalysis. The material was functionalized with acid and base active sites and used as a bifunctional catalyst in a model cascade reaction. This catalyst was recycled up to eight times with only a small loss of activity.
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