Journal
CHEMISTRY OF MATERIALS
Volume 24, Issue 11, Pages 2091-2098Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm300520w
Keywords
thermoelectric; Zintl phase; electronic transport; thermal transport
Funding
- Jet Propulsion Laboratory
- National Science Foundation
Ask authors/readers for more resources
The Zintl compound Ca5Al2Sb6 has extremely low lattice thermal conductivity (<0.6 W/mK at 1000 K) and tunable electronic properties, making it a promising thermoelectric material for high temperature waste-heat recovery. The current study investigates trends in the chemical and transport properties of the Ca5M2Sb6 compounds (M = Al, Ga, or In), revealing potential routes toward improved thermoelectric properties in this system. Here, we show that isoelectronic M-site substitutions can be used to fine-tune the electronic properties of the Ca5M2Sb6 system, without inducing electronic doping effects. Electronic structure calculations reveal that the electronegativity of the M element is a good indicator for the energy level of M electronic states. The effects of M-site substitutions on the effective mass and band gap are reflected in measurements of the high temperature electronic properties of Ca5M2Sb6 samples (M = Al, Ga, and In) which reveal increased hole mobility as well as a smaller thermal band gap in the Ga analogue, relative to Ca5Al2Sb6 and Ca5In2Sb6. Optical absorption measurements reveal a trend in the direct band gaps consistent with both calculations and transport measurements. Additionally, a direct benefit of substituting heavier elements on the Al site arises from the increased density and softer lattice, which leads to reduced sound velocity and lattice thermal conductivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available