4.8 Article

Condensed Graphitic Carbon Nitride Nanorods by Nanoconfinement: Promotion of Crystallinity on Photocatalytic Conversion

Journal

CHEMISTRY OF MATERIALS
Volume 23, Issue 19, Pages 4344-4348

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cm201688v

Keywords

template synthesis; layered materials; carbon nitrides; crystal structure; photocatalysis

Funding

  1. BMBF
  2. AvH Foundation
  3. National Natural Science Foundation of China [21033003, 21173043, U1033603]

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Photoactive, condensed carbon nitride nanorods (CNRs) can be obtained via confined thermal condensation of cyanamide inside the nanochannels of an anodic alumni oxide (AAO) membrane template. The promotion of a more condensed network of CNRs with lowered HOMO in water splitting (including both H-2 and O-2 revolution) and photocurrent output was demonstrated.

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