Journal
CHEMISTRY OF MATERIALS
Volume 23, Issue 10, Pages 2630-2636Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm200643u
Keywords
V-shaped nematogens; biaxial nematics; X-ray; conoscopy; DFT calculations
Funding
- DFG [LE 1571/2-1]
- U.S. Department of Energy (USDOE) [DE-SC0001412]
- U.S. Department of Energy, Basic Energy Sciences, Office of Science [W-31-109-Eng-38]
- U.S. Department of Energy, Basic Energy Sciences, Office of Science, through the Ames Laboratory [W-7405-Eng-82]
- U.S. Department of Energy (DOE) [DE-SC0001412] Funding Source: U.S. Department of Energy (DOE)
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The synthesis and thermotropic properties of novel V-shaped molecules having a central 1,3,4-thiadiazole core with a bend-angle of 160 are reported. The compounds consist of a shape-persistent oligo(phenylene ethynylene) scaffold with lateral alkyloxy substituents. One of the terminal aromatic units possesses an alkoxy chain capped by an ethyl ester group while the second terminus is a pyridyl group. They exhibit enantiotropic nematic phases and are characterized by polarized optical microscopy, differential scanning calorimetry, and X-ray diffraction. Results from conoscopy indicate a biaxial nature of the nematic phase near room temperature. DFT calculations of dipole moments and molecular polarizabilities are used to substantiate the experimental findings.
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