Journal
CHEMISTRY OF MATERIALS
Volume 23, Issue 5, Pages 1204-1215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm102850j
Keywords
characterization of materials; electronic materials; semiconductors
Funding
- Shanghai Natural Science Foundation [09ZR1438500]
- National Natural Science Foundation [20902105, 60901050]
- Chinese Academy of Sciences
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Four families of core-expanded naphthalene diiinide (NDI) derivatives were designed and synthesized, namely, NDI-DTYM2 (1-7, of which 1 and 2 were previously reported), NDI-DTDCN2 (8 and 9), NDI-DTYCA2 (10 and 11), and NDI-DCT2 (12), where the NDI core fuses two 2-(1,3-dithiol-2-ylidene)malonitrile (DTYM) groups, two 1,4-dithiine-2,3-dicarbonitrile (DTDCN) groups, two alkyl 2-(1,3-dithiol-2-ylidene)cyanoacetate (DTYCA) groups, and two 2,3-dicyanothiophenes (DCT), respectively. The NDI cores of the present compounds bear the branched N-alkyl substituents with the carbon atom numbers from 12 to 24, which guarantees good material solubility. The solution-processed, bottom-gate organic thin film transistors based on compounds 3-12 operate well in air with the electron mobility ranging from similar to 10(-6) to 0.26 cm(2) V-1 s(-1), depending on the nature of the branched N-alkyl substituent and the pi-backbone structure. new
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