Photophysical Properties of Near-Infrared Phosphorescent π-Extended Platinum Porphyrins

A comprehensive photophysical study is reported on a family of it-extended platinum(II) porphyrin complexes. The platinum(II) complexes are synthesized from the corresponding free base porphyrins by treatment with platinum(II) acetate in hot benzonitrile, affording the complexes in considerably higher yield than by reaction with platinum(II) chloride. A quantitative study of the absorption and luminescence properties of the metalloporphyrins is presented. A series including tetraarylbenzo-, tetraarylnaphtho-, and tetraarylanthroporphyrin exhibits efficient phosphorescence at 773, 890, and 1020 nm in the near-infrared region, with quantum yields of 0.35, 0.15, and 0.08, respectively. The triplet lifetimes and phosphorescence yields decrease with increasing emission wavelength, consistent with energy gap law behavior. A set of six Pt-tetrabenzoporphyrins (TBPs) with different meso-substituents were examined. The Pt-TBPs exhibit phosphorescence with lambda(max) similar to 770 nm and with a quantum yield ranging from 0.26-0,49, depending on the substitution pattern. The results show that the 5,15-diarylbenzoporphyrins feature 50-60% higher phosphorescence emission yield compared to the 5,10,15,20-tetraarylbenzoporphyrins. The highest phosphorescence quantum efficiency is observed for a platinum(II) 5,15-diarylbenzoporphyin which emits at 770 nm with a quantum yield of 49%.